Atropisomeric phosphinines: design and synthesis.
نویسندگان
چکیده
The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent 31P{1H} NMR spectroscopy.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 46 شماره
صفحات -
تاریخ انتشار 2007